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Low-temperature plasma degradation of high-concentration n-hexane

Lookup NU author(s): Dr Kui Zhang

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Abstract

This journal is © 2025 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique. Low-temperature plasma (LTP) degradation, a green and efficient technology, is widely used in the treatment of organic waste gases. n-Hexane is the main component of tar during biomass gasification. The treatment of high concentration n-hexane is much needed for practical applications, but it is rarely reported. In this study, the degradation process and mechanism of high concentration n-hexane under LTP treatment were investigated. The results showed that the removal efficiency of n-hexane increased with increasing specific input energy (SIE) and residence time. However, it decreased with increasing concentration under constant SIE and residence time. Under humid air conditions, with a concentration of 130 000 ppm and a residence time of 13.3 s, the maximum removal efficiency of n-hexane reached 87.6%. At the same time, the introduction of water vapor enhances the dissociation process of n-hexane, leading to increased hydrogen, CO, and CO2, improving the DBD environment, and preventing the attachment of solid residues. Through mechanism analysis, it is speculated that there are three possible conversion paths of n-hexane. This research not only fills a theoretical gap in this field but also provides a foundation for future low-temperature plasma degradation of n-hexane.


Publication metadata

Author(s): Li S, Wang Y, Li Q, Liu K, Liu N, Liao G, Xin Z, Feng Z, Zhang K

Publication type: Article

Publication status: Published

Journal: New Journal of Chemistry

Year: 2025

Volume: 49

Issue: 46

Pages: 20138-20150

Print publication date: 14/12/2025

Online publication date: 11/11/2025

Acceptance date: 14/10/2025

ISSN (print): 1144-0546

ISSN (electronic): 1369-9261

Publisher: Royal Society of Chemistry

URL: https://doi.org/10.1039/d5nj02254a

DOI: 10.1039/d5nj02254a


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