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Trifunctional Rare‐Metal‐Free Electrocatalysts Prepared Entirely from Biomass

Lookup NU author(s): Dr Manjit GrewalORCiD

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This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).


Abstract

As part of ongoing efforts to realize a low-carbon and hydrogen-based society,there is an increasing demand for high-performance electrocatalysts, which arekey materials for fuel cells and water electrolysis systems. Although platinumgroup metals exhibit high catalytic activity, increasing production costs due toresource constraints, limited countries of production, and geopolitical supplyissues are threatening their use. Therefore, it is crucial to make substantialchanges in resource utilization for the sustainable production of electrochemicalcatalysts. Herein, the preparation of trifunctional biomass-derived electrocata-lysts for the oxygen reduction reaction and oxygen/hydrogen evolution reactionsby the pyrolysis of cellulose nanofibers from ascidian tunicates, dried blood meal,and cyanocobalamin is reported. The combination of N, P, FeN 4 , and CoN 4structures incorporated in the carbon network leads to high electrochemicalperformance comparable with rare-metal-based electrocatalysts and other carbonalloy electrocatalysts. This work provides a possible strategy for fabricating high-capacity energy storage devices from biomass resources such as industrial wastewithout the need for rare metals or other harmful heavy metals.


Publication metadata

Author(s): Ishibashi K, Grewal MS, Ito K, Shoji N, Matsuo Y, Yabu H

Publication type: Article

Publication status: Published

Journal: Advanced Energy and Sustainability Research

Year: 2022

Volume: 3

Issue: 11

Print publication date: 01/11/2022

Online publication date: 16/09/2022

Acceptance date: 18/08/2022

Date deposited: 21/01/2026

ISSN (electronic): 2699-9412

Publisher: Wiley-VCH Verlag GmbH & Co. KGaA

URL: https://doi.org/10.1002/aesr.202200107

DOI: 10.1002/aesr.202200107

Data Access Statement: The data that support the findings of this study are available from the corresponding author upon reasonable request.


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Funding

Funder referenceFunder name
Japan Society for the Promotion of Science. Grant Numbers: 18H05482, 19KK0357, 22K19077
MEXT, Japan. Grant Number: JPMXP1222HK0010
New Energy and Industrial Technology Development Organization. Grant Number: 2020-0115004

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