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Reviews and syntheses: Carbon vs. cation based MRV of Enhanced Rock Weathering and the issue of soil organic carbon

Lookup NU author(s): Dr Tom ReershemiusORCiD

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This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).


Abstract

We discuss the “monitoring, reporting and verification” (MRV) strategy of Enhanced Weathering (EW) based on carbon accounting and argue that in open systems such as arable land, this approach is ill-suited to close the balance of all carbon fluxes. We argue for total alkalinity (TA) as the central parameter for the carbon based MRV of EW. However, we also stress that tracking alkalinity fluxes using a systems-level approach is best done by focusing on charge balance maintenance through time. We start by explaining the concept and history of alkalinity conceptualization for the oceans. The same analytical method first proposed for the oceans – titration with a strong acid – is now commonly used for porewaters in agricultural soils. We explain why this is an accurate analysis for ocean water and why it is unsuitable to record TA for porewaters in agricultural soils. We then introduce an alternative MRV based on cation accounting and finally discuss the fate of cations released from the weathering of basalt, soil cation dynamics and close by suggesting open research questions.


Publication metadata

Author(s): Bijma J, Hagens M, Hammes JS, Planavsky N, Pogge von Strandmann PAE, Reershemius T, Reinhard CT, Renforth P, Suhrhoff TJ, Vicca S, Vienne A, Wolf-Gladrow D

Publication type: Article

Publication status: Published

Journal: Biogeosciences

Year: 2026

Volume: 23

Issue: 1

Pages: 53-75

Print publication date: 05/01/2026

Online publication date: 05/01/2026

Acceptance date: 27/11/2025

Date deposited: 05/01/2026

ISSN (print): 1726-4170

ISSN (electronic): 1726-4189

Publisher: Copernicus GmbH

URL: https://doi.org/10.5194/bg-23-53-2026

DOI: 10.5194/bg-23-53-2026

Data Access Statement: No data sets were used in this article.


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Funding

Funder referenceFunder name
Alfred-Wegener-Institut Helmholtz-Zentrum für Polar- und Meeresforschung
Paessler Family Foundation
Swiss National Science Foundation (grant no. P500PN_210790)
Yale Center for Natural Carbon Capture

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