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H2O2-Assisted Sunlight Photocatalytic Degradation of Basic Fuchsin Using Green-Synthesized ZnO Nanowires

Lookup NU author(s): Dr Jie ZhangORCiD

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This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).


Abstract

© 2026 by the authors.The efficient removal of toxic dyes from wastewater remains a major environmental challenge. In this study, we report a green and facile one-pot synthesis of zinc oxide nanowires (ZnO-NWs) using lemon verbena leaf extract as a sustainable capping and stabilizing agent. The extract played a vital role in directing the 1D growth of the wurtzite hexagonal structure. Characterization confirmed a band gap of 3.12 eV and the characteristic Zn-O stretching at 375 cm−1. Photocatalytic activity tests using 20 mg of biosynthesized ZnO-NWs demonstrated excellent degradation performance. A rate constant of 0.0067 min−1 was achieved, with 99.95% degradation of Basic Fuchsin under natural sunlight for 3 h. Active species analysis highlighted the crucial roles of holes (h+), superoxide radicals (O2•−), and hydroxyl radicals (•OH). Notably, the addition of 10 mM H2O2 produced a powerful synergistic effect, reducing the degradation time from 3 h to only 7 min and increasing the reaction rate by approximately 25-fold. These findings highlight the potential of biosynthesized ZnO-NWs as highly efficient, rapid, and sustainable photocatalysts for environmental remediation.


Publication metadata

Author(s): Hazmoune A, Boukaous C, Iaiche S, Benhaoua B, Fadhillah F, Assadi AA, Amrane A, Ali FAA, Zhang J, Kebir M, Tahraoui H

Publication type: Article

Publication status: Published

Journal: Catalysts

Year: 2026

Volume: 16

Issue: 2

Online publication date: 17/02/2026

Acceptance date: 13/02/2026

Date deposited: 09/03/2026

ISSN (electronic): 2073-4344

Publisher: MDPI

URL: https://doi.org/10.3390/catal16020193

DOI: 10.3390/catal16020193

Data Access Statement: The original contributions presented in this study are included in the article. Further inquiries can be directed to the corresponding authors


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Funding

Funder referenceFunder name
Deanship of Scientific Research at Imam Mohammad Ibn Saud Islamic University

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