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Vapour phase exciplex formation between 1,4-Dicyanonaphthalene and 2,5-Dimethyl-2,4-hexadiene

Lookup NU author(s): Dr Geoffrey AbbottORCiD

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Abstract

Fluorescence has been observed from the exciplex formed between electronically excited 1,4-dicyanonaphthalene and 2,5-dimethyl-2,4-hexadiene in the vapour phase and the kinetics of exciplex formation studied. The enthalphy of vapour-phase exciplex formation in this pair of molecules was found to be 8 kJ mol^–1 and activation energies for formation and reverse dissociation of the exciplex were found to be 15 and 23 kJ mol^–1, respectively.

Publication metadata

Author(s): Abbott GD, O'Connor DV, Phillips D

Publication type: Article

Publication status: Published

Journal: Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Year: 1981

Volume: 77

Issue: 6

Pages: 1381-1392

ISSN (print): 0300-9599

ISSN (electronic): 1463-9084

URL: http://dx.doi.org/10.1039/f19817701381

DOI: 10.1039/f19817701381

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