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Triplet-triplet absorption spectra of some benzenoid hydrocarbons in the vapour phase

Lookup NU author(s): Dr Geoffrey AbbottORCiD


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An apparatus capable of measuring triplet–triplet absorption spectra in the 200–300 nm region for molecules with triplet lifetimes in the 1 ms–100 ns region is described. Spectra obtained for some fluoro-, methyl- and trifluoromethyl-substituted benzenes in the vapour phase are assigned using CNDO/S calculations. Comparison is made with predictions from other calculations.

Publication metadata

Author(s): Abbott GD, Dyke J, Phillips D, Sime ME

Publication type: Article

Publication status: Published

Journal: Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

Year: 1982

Volume: 78

Pages: 1971-1980

ISSN (print): 0956-5000

ISSN (electronic): 1463-9084


DOI: 10.1039/f29827801971


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