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Lookup NU author(s): Professor Alan Dickinson
A semiclassical result is derived for the scattering volume for near-threshold p-wave scattering by a potential falling off as 1/R^n, n >= 6, R being the interatomic separation. This result depends only on the s-wave zero-energy classical action and properties of the long-range potential and hence can be related to the semiclassical result for the scattering length. The exact result for the scattering volume for the Lennard-Jones (2n-2,n), n >=6 is derived and it is shown that the corresponding semiclassical result is within 1% for potentials supporting at least two rotationless bound levels. Comparisons are made for the scattering volume with a variety of results in the literature for a range of systems supporting between 0 and 83 rotationless bound levels. The semiclassical result is generally within 5% and was never in error by more than 15%, which occurred for a case supporting no bound states.
Author(s): Dickinson AS
Publication type: Article
Publication status: Published
Journal: Journal of Physics B: Atomic, Molecular and Optical Physics
Year: 2008
Volume: 41
Issue: 175302
Pages: 5
Date deposited: 27/08/2008
ISSN (print): 0953-4075
ISSN (electronic): 1361-6455
Publisher: Institute of Physics
URL: http://dx.doi.org/10.1088/0953-4075/41/17/175302
DOI: 10.1088/0953-4075/41/17/175302
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