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Metallaborane reaction chemistry: Part 8. Phenylacetylene trimerisation by [6,6,6-(PPh3)2H-nido-6-IrB9H13] and the structure of [2-(η6-C6H3Ph3)-closo-2-IrB 9H8-10-(PPh3)] by synchrotron X-ray diffraction analysis

Lookup NU author(s): Professor William Clegg

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Abstract

The microwave-heated reaction between PhCCH and [6,6,6-(PPh3)2H-nido-6-IrB9H13] gives [2-(η6-C6H3Ph3)-closo-2-IrB 9H6-10-(PPh3)] (29%) and thereby demonstrates acetylene trimerisation on a metallaborane matrix.

Publication metadata

Author(s): Bould J, Clegg W, Spalding TR, Kennedy JD

Publication type: Article

Publication status: Published

Journal: Inorganic Chemistry Communications

Year: 1999

Volume: 2

Issue: 7

Pages: 315-318

Print publication date: 01/07/1999

ISSN (print): 1387-7003

ISSN (electronic): 1879-0259

Publisher: Elsevier

URL: http://dx.doi.org/10.1016/S1387-7003(99)00076-3

DOI: 10.1016/S1387-7003(99)00076-3

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