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Lookup NU author(s): Dr John ErringtonORCiD,
Dr Gary Walker,
Emeritus Professor Bill CleggORCiD,
Dr Lynne Horsburgh
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The new molecular phenoxides [BaB2(OPh)8(thf)4] 1 and [BaB2(OPh)8(dme)2] 2 have been synthesised from B(OPh)3 and either a preformed barium phenoxide or barium metal in the presence of phenol; X-ray structure determinations reveal that the barium is eight-coordinate in both compounds and that the chelating [B(OPh)4]- groups occupy trans positions in 1 but cis positions in 2.
Author(s): Errington RJ, Tombul M, Walker GLP, Clegg W, Heath SL, Horsburgh L
Publication type: Article
Publication status: Published
Journal: Journal of the Chemical Society - Dalton Transactions
Print publication date: 21/10/1999
ISSN (print): 1472-7773
ISSN (electronic): 1364-5447
Publisher: The Royal Society of Chemistry
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