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Chalcogenide-bridged cuboidal clusters with M4Q4 (M = Mo, W; Q = S, Se, Te) cores

Lookup NU author(s): Emeritus Prof Alfred Sykes

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Abstract

Cuboidal cluster complexes having M4Q4 cores made up of transition and main group metals (M), and non-metallic e.g. chalcogenide elements (Q), constitute a rapidly expanding area of inorganic chemistry. Extensive preparation, structural and reactivity studies have been carried out on the Group 6 metals (M = Mo, W) and chalcogenide (Q = S, Se, Te) clusters, and are the main focus of this perspective. The aqueous solution chemistry provides an important reference point in considering redox and other relevant properties. © The Royal Society of Chemistry 1999.

Publication metadata

Author(s): Hernandez-Molina R, Sykes AG

Publication type: Article

Publication status: Published

Journal: Journal of the Chemical Society - Dalton Transactions

Year: 1999

Volume: 1999

Issue: 18

Pages: 3137-3148

Print publication date: 01/01/1999

ISSN (print): 1477-9226

ISSN (electronic):

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/A904740I

DOI: http://dx.doi.org/10.1039/A904740I

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