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An insight into ion-transport by calixarenes; the structure of the dipotassium complex of p-tert-butylcalix[8]arene crystallised from a protogenic, coordinating solvent [ethanol/diethylcarbonate (10:1)]

Lookup NU author(s): Emeritus Professor Bill Clegg

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Abstract

The structure of the dipotassium complex of the dianion of p-tert-butylcalix[8]arene crystallised from a protogenic, coordinating solvent (ethanol-diethylcarbonate, 10:1) shows that the metal ions are bound above and below the cavity of the calix[8]arene, which adopts a 'pinched' conformation.


Publication metadata

Author(s): Clague NP, Clegg W, Coles SJ, Crane JD, Moreton DJ, Sinn E, Teat SJ, Young NA

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 1999

Volume: 1999

Issue: 4

Pages: 379-380

Print publication date: 01/01/1999

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/a809401b

DOI: 10.1039/a809401b


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