Browse by author
Lookup NU author(s): Dr Mark Elsegood,
Emeritus Professor Bill Clegg
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
Treatment of ScCl3·THF3 with the lithium salts of the ligands ArNC(R)CHC(R)NAr, where Ar = 2,6-Pr1-C6H3 and R = CH3 and But, gives LScCl2·nTHF derivatives (R = CH3, n = 1, 1a; R = But, n = 0, 1b). These compounds can be derivatized by alkylation with methyllithium or benzylpotassium. The dibenzyl compound prepared from 1a, when treated with B(CcFc)S, gives an ion pair, 4, in which the cationic scandium center is stabilized by a η6-aryl interaction with the abstracted borate benzyl group.
Author(s): Lee LWM, Piers WE, Elsegood MRJ, Clegg W, Parvez M
Publication type: Article
Publication status: Published
Print publication date: 02/08/1999
ISSN (print): 0276-7333
ISSN (electronic): 1520-6041
Publisher: American Chemical Society
Altmetrics provided by Altmetric