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Lookup NU author(s): Emeritus Professor Bill CleggORCiD,
Dr Stephen Liddle
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Made by a nitrile insertion/hydrogen migration process via Ph2P(O)CH2Li and ButCN, the enamide Ph2P(O)CH= C(But)N(H)Li and its TMEDA hemisolvate exist as tetrameric and dinuclear arrangements respectively: the novel structure of the starting lithiated phosphane oxide, also in its TMEDA hemisolvated form, is shown to contain Li-C contacts of two distinct types.
Author(s): Clegg W, Davies RP, Dunbar L, Feeder N, Liddle ST, Mulvey RE, Snaith R, Andrew E, Wheatley H
Publication type: Article
Publication status: Published
Journal: Chemical Communications
Print publication date: 01/01/1999
ISSN (print): 1359-7345
ISSN (electronic): 1364-548X
Publisher: Royal Society of Chemistry
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