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Direct methanol polymer electrolyte fuel cell: Analysis of charge and mass transfer in the vapour-liquid-solid system

Lookup NU author(s): Emeritus Professor Keith Scott

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Abstract

Liquid-feed direct methanol fuel cell systems (DMFC) have a number of advantages over hydrogen fuel cells. For a DMFC no additional fuel processing is necessary, therefore, it has a lower volume and a lower weight, the existing infrastructure for fuel supply and distribution can be utilized and the fuel costs are low. However, a number of technical problems have still to be solved. The most important are the cross-over of methanol through the polymer electrolyte membrane, the removal of carbon dioxide from the anode catalyst layer, and the poor anode kinetics. These aspects are analysed by means of a steady state, isothermal cell model which accounts for the essential mass and charge transport processes in the different fuel cell layers. The model is applied to evaluate experimental current-voltage data which were obtained from a small scale cell fuelled with liquid methanol/water solutions.


Publication metadata

Author(s): Scott K; Sundmacher K

Publication type: Article

Publication status: Published

Journal: Chemical Engineering Science

Year: 1999

Volume: 54

Issue: 13-14

Pages: 2927-2936

Print publication date: 01/07/1999

ISSN (print): 0009-2509

ISSN (electronic): 1873-4405

Publisher: Elsevier Science Ltd

URL: http://dx.doi.org/10.1016/S0009-2509(98)00344-3

DOI: 10.1016/S0009-2509(98)00344-3


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