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Metal incorporation into and dimerization of M3E4 clusters (M = Mo, W; E = S, Se) in supramolecular assemblies with cucurbituril: A molecular model of intercalation

Lookup NU author(s): Dr Maxim Sokolov, Professor William Clegg, Emeritus Prof Alfred Sykes

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Abstract

Structural models for the incorporation of metal atoms into layered dichalcogenides, ME2, are provided by two series of isostructural hybrid organic-inorganic supramolecular assemblies based on cucurbituril adducts of incomplete cuboidal aqua cluster complexes of molybdenum and tungsten, and heterometallic corner-shared double cube derivatives. The picture illustrates the structure of the assembly [{[Mo3Se4(H2O)7Cl2]2Hg}(C36H36N24O12)](n)/(4n+).

Publication metadata

Author(s): Sokolov MN, Virovets AV, Dybtsev DN, Gerasko OA, Fedin VP, Hernandez-Molina R, Clegg W, Sykes AG

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie - International Edition

Year: 2000

Volume: 39

Issue: 9

Pages: 1659-1661

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - VCH Verlag GmbH & Co

URL: http://dx.doi.org/10.1002/(SICI)1521-3773(20000502)39:9<1659::AID-ANIE1659>3.0.CO;2-8

DOI: 10.1002/(SICI)1521-3773(20000502)39:9<1659::AID-ANIE1659>3.0.CO;2-8

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