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B-frame supported bimetallics. 'Composite cluster' compounds and the structures of [2,7-(η5-C5Me5) 2-nido-2,7,8,6-Ir2CSB6H8] and its 9-chloro derivative. Synchrotron and conventional X-ray studies

Lookup NU author(s): Emeritus Professor Bill Clegg

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Abstract

Reaction of [IrCl2(η5-C5Me5)]2 with the [hypho-CSB6H11]- anion gives [2,7-(η5-C5Me5) 2-nido-2,7,8,6-Ir2CSB6H8] and [2,7-(η5-C5Me5) 2-nido-2,7,8,6-Ir2CSB6H7-9-Cl] which exhibit composite cluster features in which the {IrSIrC} string and the {B6} unit occupy separate domains within the overall contiguous nido-type ten-vertex {Ir2SCB6} cluster unit. © 2000 Elsevier Science B.V.


Publication metadata

Author(s): Cooke PA, O'Dowd C, Londesborough MGS, Holub J, Stibr B, Thornton-Pett M, Clegg W, Teat SJ, Kennedy JD

Publication type: Article

Publication status: Published

Journal: Journal of Organometallic Chemistry

Year: 2000

Volume: 614-615

Pages: 57-60

ISSN (print): 0022-328X

ISSN (electronic): 1872-8561

Publisher: Elsevier

URL: http://dx.doi.org/10.1016/S0022-328X(00)00592-1

DOI: 10.1016/S0022-328X(00)00592-1


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