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Supramolecular assemblies based on cucurbituril adducts of hydrogen-bonded molybdenum and tungsten incomplete cuboidal aqua complexes

Lookup NU author(s): Professor William Clegg

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Abstract

Six cis coordinated H2O molecules of the triangular cluster complexes M3(μ3-S)(μ2-S)3(H2O)9]4+ (M = Mo, W) (hydrogen bond donors) complementary to six portal oxygen atoms of cucurbituril (acceptors). The shape and symmetry of the building blocks induce specific crystal structures.

Publication metadata

Author(s): Fedin VP, Virovets AV, Sokolov MN, Dybtsev DN, Gerasko OA, Clegg W

Publication type: Article

Publication status: Published

Journal: Inorganic Chemistry

Year: 2000

Volume: 39

Issue: 10

Pages: 2227-2230

Print publication date: 15/05/2000

ISSN (print): 0020-1669

ISSN (electronic): 1520-510X

Publisher: American Chemical Society

URL: http://dx.doi.org/10.1021/ic000026r

DOI: 10.1021/ic000026r

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