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The first Ru(II) bipyridyl-capped cyclodextrin: Evidence of electron- transfer through the cavity

Lookup NU author(s): Emeritus Professor Anthony Harriman

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Abstract

The narrow rim of an α-cyclodextrin has been AD-capped with a photoactive ruthenium(II) tris(2,2'-bipyridyl) fragment giving a diastereomeric mixture of complexes that bind 1,4-benzoquinone in water. Steady-state and time-resolved emission studies have been used to probe electron-transfer processes occurring inside and outside the cavity.

Publication metadata

Author(s): Armspach D, Matt D, Harriman A

Publication type: Article

Publication status: Published

Journal: European Journal of Inorganic Chemistry

Year: 2000

Volume: 2000

Issue: 6

Pages: 1147-1150

ISSN (print): 1434-1948

ISSN (electronic): 1099-0682

Publisher: Wiley - VCH Verlag GmbH & Co

URL: http://dx.doi.org/10.1002/(SICI)1099-0682(200006)2000:6<1147::AID-EJIC1147>3.3.CO;2-U

DOI: 10.1002/(SICI)1099-0682(200006)2000:6<1147::AID-EJIC1147>3.3.CO;2-U

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