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Lookup NU author(s): Emeritus Professor Anthony Harriman,
Professor Andrew Benniston
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Long-range interactions over 50 Å allow electron exchange to proceed in a series of conformationally constrained Ru/Os polypyridine complexes (see picture). The dynamics of the intramolecular electron exchange indicate that the connecting 1,4-diethynylated-2,5-dialkoxybenzene units act independently as superexchange mediators. Even with five such units linked together there is no indication for the population of a connector-based triplet state.
Author(s): Harriman A, Khatyr A, Ziessel R, Benniston AC
Publication type: Article
Publication status: Published
Journal: Angewandte Chemie - International Edition
ISSN (print): 1433-7851
ISSN (electronic): 1521-3773
Publisher: Wiley - VCH Verlag GmbH & Co
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