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A three-dimensional, cyano-bridged cluster-metal coordination compound with large cavities

Lookup NU author(s): Dr Mark Elsegood, Emeritus Professor Bill Clegg

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Abstract

By very slow diffusion of aqueous solutions of CoCl2·6H2O and K6[W4Te4(CN)12]·5H 2O through silica gel, single crystals of [Co(H2O)4]3[W4Te 4(CN)12]·15.38H2O were obtained. A complete X-ray structure determination reveals an extremely porous, three-dimensional neutral cluster-expanded framework structure with large water-filled cuboidal cavities. © Wiley-VCH Verlag GmbH, 2000.


Publication metadata

Author(s): Fedin VP, Virovets AV, Kalinina IV, Ikorskii VN, Elsegood MRJ, Clegg W

Publication type: Article

Publication status: Published

Journal: European Journal of Inorganic Chemistry

Year: 2000

Issue: 11

Pages: 2341-2343

ISSN (print): 1434-1948

ISSN (electronic): 1099-0682

Publisher: Wiley - VCH Verlag GmbH & Co

URL: http://dx.doi.org/10.1002/1099-0682(200011)2000:11<2341::AID-EJIC2341>3.0.CO;2-1

DOI: 10.1002/1099-0682(200011)2000:11<2341::AID-EJIC2341>3.0.CO;2-1


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