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Solid and solution state structures of a reversible molecular oxygen-carrying molybdenum porphyrin dioxygen complex

Lookup NU author(s): Emeritus Professor William McFarlane

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Abstract

The molecular structure of a reversible oxygen carrier, MoVIO(tmp)(O2) has been characterized by X-ray crystallography. Oxo and dioxygen ligands are actually coordinated with cis conformation, which leads to a saddle-like distortion of the porphyrin ring. The result of 2D ROESY shows the distortion of the porphyrin ring is retained in solution.

Publication metadata

Author(s): Fujihara T, Rees NH, Umakoshi K, Tachibana J, Sasaki Y, McFarlane W, Imamura T

Publication type: Article

Publication status: Published

Journal: Chemistry Letters

Year: 2000

Volume: 29

Issue: 2

Pages: 102-103

Print publication date: 01/01/2000

ISSN (print): 0366-7022

ISSN (electronic): 1348-0715

Publisher: Chemical Society of Japan

URL: http://dx.doi.org/10.1246/cl.2000.102

DOI: 10.1246/cl.2000.102

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