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Lookup NU author(s): Professor William Clegg
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The title compound, hexaammonium tetra-μ3-selenido-tetrakis(tricyanomolybdenum) hexahydrate, is isostructural with the Mo/S, W/S and W/Se analogues. The structure contains disordered cyclic hydrogen-bonded [{(NH4)(H2O)}3]3+ cations and [Mo4Se4(CN)12]6- cluster anions with 4̄3m symmetry. The cation assembly consists of alternating ammonium and water molecules linked by N-H⋯O hydrogen bonds. The anion has a typical cubane cluster structure. The cations and anions are linked together by hydrogen bonds involving the terminal N atoms of the CN groups.
Author(s): Virovets AV, Fedin VP, Samsonenko DG, Clegg W
Publication type: Article
Publication status: Published
Journal: Acta Crystallographica Section C: Crystal Structure Communications
Year: 2000
Volume: 56
Issue: 3
Pages: 272-273
ISSN (print): 0108-2701
ISSN (electronic): 1600-5759
Publisher: Wiley-Blackwell Publishing Ltd.
URL: http://dx.doi.org/10.1107/S0108270199015644
DOI: 10.1107/S0108270199015644
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