Browse by author
Lookup NU author(s): Dr Petr Illarionov, Dr Ian Hancock
Full text for this publication is not currently held within this repository. Alternative links are provided below where available.
Uridine 5′-(2-acetamido-2,6-dideoxy-β-L-galactopyranosyl) diphosphate (uridine 5′-diphospho-N-acetyl-β-L-fucosamine) was synthesized. The key intermediate, 3,4-di-O-acetyl-2-azido-2,6-dideoxy-β-L-galactopyranosyl dibenzyl phosphate, was prepared by a previously unknown reaction of cesium dibenzyl phosphate with the corresponding α-glycosyl nitrate and was then converted into the N-acetylated glycosyl phosphate and nucleoside diphosphate sugars via 3,4-di-O-acetyl-2-amino-2,6-dideoxy-β-L-galactopyranosyl phosphate using mild N-acetylation and O-deacetylation as the last synthetic steps.
Author(s): Hancock I; Illarionov PA; Torgov VI; Shibaev VN
Publication type: Article
Publication status: Published
Journal: Russian Chemical Bulletin
Year: 2000
Volume: 49
Issue: 11
Pages: 1891-1894
ISSN (print): 1066-5285
ISSN (electronic): 1573-9171
Publisher: Springer New York LLC
URL: http://www.chemweb.com/journals/journals?type=issue&jid=SV11172&iid=0004900011