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Charge transfer salts of the lanthanides: The crystal structure of [Yb(TpMe,Me)2][TCNE]·(THF)6

Lookup NU author(s): Dr Mark Elsegood

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Abstract

The reaction of [Ln(TpMe,Me)2] (Ln=Sm, Eu, Yb) with TCNE and TCNQ gave good yields of the expected salt [Ln(TpMe,Me)2]Y (Y=TCNE, TCNQ) as a THF solvate. The crystal structure of [Yb(TpMe,Me)2][TCNE]·(THF)6 was determined and shows the expected salt-like formulation, but shows no significant interionic contacts. The reactions with TCNQ produced less well-defined products with evidence for interionic contacts. © 2001 Elsevier Science B.V.

Publication metadata

Author(s): Maunder GH, Sella A, Elsegood MRJ

Publication type: Article

Publication status: Published

Journal: Journal of Organometallic Chemistry

Year: 2001

Volume: 619

Issue: 1-2

Pages: 152-156

ISSN (print): 0022-328X

ISSN (electronic): 1872-8561

Publisher: Elsevier S.A.

URL: http://dx.doi.org/10.1016/S0022-328X(00)00691-4

DOI: 10.1016/S0022-328X(00)00691-4

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