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Lookup NU author(s): Emeritus Professor Bill Clegg,
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Facile insertion of elemental Se or Te into the C-Li bond of nBuLi in the presence of TMEDA gives [nBuXLi·TMEDA]2 (X = Se 1; Te 2). Both 1 and 2 have been fully characterised in the solid and solution states resulting in the first crystal structures of a lithium alkylselenolate and -tellurolate and giving a unique insight into the coordination chemistry of the less sterically demanding chalcogenolate ligands.
Author(s): Clegg W, Davies RP, Snaith R, Wheatley AEH
Publication type: Article
Publication status: Published
Journal: European Journal of Inorganic Chemistry
ISSN (print): 1434-1948
ISSN (electronic): 1099-0682
Publisher: Wiley - VCH Verlag GmbH & Co
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