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Lithium alkylselenolates and -tellurolates - A solid-state and solution structural study

Lookup NU author(s): Emeritus Professor Bill Clegg, Ronald Davies

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Abstract

Facile insertion of elemental Se or Te into the C-Li bond of nBuLi in the presence of TMEDA gives [nBuXLi·TMEDA]2 (X = Se 1; Te 2). Both 1 and 2 have been fully characterised in the solid and solution states resulting in the first crystal structures of a lithium alkylselenolate and -tellurolate and giving a unique insight into the coordination chemistry of the less sterically demanding chalcogenolate ligands.


Publication metadata

Author(s): Clegg W, Davies RP, Snaith R, Wheatley AEH

Publication type: Article

Publication status: Published

Journal: European Journal of Inorganic Chemistry

Year: 2001

Volume: 2001

Issue: 6

Pages: 1411-1413

ISSN (print): 1434-1948

ISSN (electronic): 1099-0682

Publisher: Wiley - VCH Verlag GmbH & Co

URL: http://dx.doi.org/10.1002/1099-0682(200106)2001:6<1411::AID-EJIC1411>3.0.CO;2-M

DOI: 10.1002/1099-0682(200106)2001:6<1411::AID-EJIC1411>3.0.CO;2-M


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