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Behavioral patterns of heterometallic cuboidal derivatives of [M3Q4(H2O)9]4+ (M = Mo, W; Q = S, Se)

Lookup NU author(s): Dr Maxim Sokolov, Emeritus Prof Alfred Sykes

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Abstract

This Account reports recent progress in the study of some ∼20 heterometal derivatives of [Mo3S4(H2O)9]4+ with reference also to W and Se analogues. Single cubes (3:1) and corner-shared double cubes (6:1), as well as dimers of the 3:1 single cubes, are considered. A classification of the heterometals as subtypes A, B, and C is introduced.

Publication metadata

Author(s): Hernandez-Molina R, Sokolov MN, Sykes AG

Publication type: Article

Publication status: Published

Journal: Accounts of Chemical Research

Year: 2001

Volume: 34

Issue: 3

Pages: 223-230

Print publication date: 01/01/2001

ISSN (print): 00014842

ISSN (electronic):

DOI: 10.1021/ar960152s

PubMed id: 11263880

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