Toggle Main Menu Toggle Search

Open Access padlockePrints

The Newcastle University research output collection, currently available on ePrints, will shortly be moving to a new open repository platform, Figshare. To prepare for the data migration we have paused adding new content to ePrints, and will resume once the new repository is launched. During this time you will continue to have access to ePrints (but no new content will appear). We will share updates here when available.

First evidence of fast S-H ··· S proton transfer in a transition metal complex

Lookup NU author(s): Professor William Clegg

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.

Abstract

Despite the weakness of S-H ··· S interactions and the fact that they have rarely been reported in transition-metal compounds, variable-temperature NMR data and theoretical calculations provide evidence for fast intramolecular proton exchange between the bridging sulfur atoms in the complexes [Pt2{Ph2P(CH2)n PPh2}2(μ-S)(μ-SH)]ClO4 (n = 2, 3; see scheme).

Publication metadata

Author(s): Aullon G, Capdevila M, Clegg W, Gonzalez-Duarte P, Lledos A, Mas-Balleste R

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie: International Edition

Year: 2002

Volume: 41

Issue: 15

Pages: 2776-2778

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - V C H Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/1521-3773(20020802)41:15<2776::AID-ANIE2776>3.0.CO;2-0

DOI: 10.1002/1521-3773(20020802)41:15<2776::AID-ANIE2776>3.0.CO;2-0

PubMed id: 12203482

Altmetrics

Altmetrics provided by Altmetric

Share