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First evidence of fast S-H ··· S proton transfer in a transition metal complex

Lookup NU author(s): Professor William Clegg

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Abstract

Despite the weakness of S-H ··· S interactions and the fact that they have rarely been reported in transition-metal compounds, variable-temperature NMR data and theoretical calculations provide evidence for fast intramolecular proton exchange between the bridging sulfur atoms in the complexes [Pt2{Ph2P(CH2)n PPh2}2(μ-S)(μ-SH)]ClO4 (n = 2, 3; see scheme).

Publication metadata

Author(s): Aullon G, Capdevila M, Clegg W, Gonzalez-Duarte P, Lledos A, Mas-Balleste R

Publication type: Article

Publication status: Published

Journal: Angewandte Chemie: International Edition

Year: 2002

Volume: 41

Issue: 15

Pages: 2776-2778

ISSN (print): 1433-7851

ISSN (electronic): 1521-3773

Publisher: Wiley - V C H Verlag GmbH & Co. KGaA

URL: http://dx.doi.org/10.1002/1521-3773(20020802)41:15<2776::AID-ANIE2776>3.0.CO;2-0

DOI: 10.1002/1521-3773(20020802)41:15<2776::AID-ANIE2776>3.0.CO;2-0

PubMed id: 12203482

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