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Stabilization of the previously unknown tautomer HP(OH)2 of hypophosphorous acid as ligand; preparation of [W3(NI(HP(OH)2))Q4(H2O)9]4+ (Q = S, Se) complexes

Lookup NU author(s): Professor William Clegg

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Abstract

Bis(hydroxy)phosphine, the isomer of hypophosphorous acid which remained elusive for a long time, coordinates to the Ni site of heterometallic clusters with a W3NiQ4 core (Q = S, Se) to give [W3(Ni(HP(OH)2))Q4(H2O 9]4+ Q = S, Se).

Publication metadata

Author(s): Sokolov MN, Hernandez-Molina R, Clegg W, Fedin VP, Mederos A

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2003

Volume: 9

Issue: 1

Pages: 140-141

Print publication date: 01/01/2003

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b209792c

DOI: 10.1039/b209792c

PubMed id: 12611005

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