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tert-Butyl (2R)-2-(9H-fluoren-9-ylmethoxy-carbonylamino)-3-iodopropionate

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Lynne Horsburgh

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Abstract

The title compound, C22H24INO4 is a chiral reagent developed and used for the synthesis of unnatural amino acids. It forms chains in its crystal structure, via weak N - H⋯O=C hydrogen bonds. The bulky iodo substituent lies gauche to the two substituents on the neighbouring C atom, about a C - C single bond, rather than gauche to one and trans to the other. This does not seem to be a consequence of any significant intermolecular interactions. The absolute configuration has been confirmed by this experiment and is as expected from the synthesis. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.


Publication metadata

Author(s): Clegg W, Horsburgh L

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2003

Volume: 59

Issue: 12

Pages: o1925-o1926

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell

URL: http://dx.doi.org/10.1107/S1600536803025467

DOI: 10.1107/S1600536803025467


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