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(Trans-cinnamaldehyde)tris(2,6-diphenylphenoxy)aluminium

Lookup NU author(s): Professor William Clegg, Dr Mark Elsegood

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Abstract

The title compound, [Al(C18H13O)3(C 9H8O)], crystallizes with three molecules in the asymmetric unit of the chiral trigonal space group P32. The three molecules have essentially the same geometry, and are related by non-crystallographic translation and other pseudosymmetry, all being in approximately the same orientation. Aluminium has a typical tetrahedral coordination. Al-O bond lengths range from 1.695 (3) to 1.716 (3) Å for the bulky substituted phenoxy ligands, and from 1.830 (4) to 1.841 (4) Å for the neutral transcinnamaldehyde ligands. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.

Publication metadata

Author(s): Clegg W, Elsegood MRJ, Snaith R, Wheatley AEH

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2003

Volume: 59

Issue: 5

Pages: m225-m227

Print publication date: 01/05/2003

ISSN (print): 1600-5368

ISSN (electronic):

Publisher: Wiley-Blackwell Publishing

URL: http://dx.doi.org/10.1107/S1600536803007141

DOI: 10.1107/S1600536803007141

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