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Building molecular-scale bridges having restricted rotation

Lookup NU author(s): Professor Andrew Benniston, Emeritus Professor Anthony Harriman, Dr Peiyi Li, Craig Sams

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Abstract

The synthesis is reported of a binuclear ruthenium(II) bis(2,2′:6′,2″-terpyridine) complex for which the polytopic ligand incorporates a central, torsionally-constrained biphenylene group. In principle, the dihedral angle between the two phenylene rings can be controlled by the length of the constraining strap. © 2003 Elsevier Science Ltd. All rights reserved.

Publication metadata

Author(s): Benniston AC, Harriman A, Li P, Sams CA

Publication type: Article

Publication status: Published

Journal: Tetrahedron Letters

Year: 2003

Volume: 44

Issue: 22

Pages: 4167-4169

ISSN (print): 0040-4039

ISSN (electronic): 1873-3581

Publisher: Pergamon

URL: http://dx.doi.org/10.1016/S0040-4039(03)00932-8

DOI: 10.1016/S0040-4039(03)00932-8

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