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Hydrodehalogenation of 2,4-dibromophenol by electrochemical reduction

Lookup NU author(s): Dr Hua Cheng, Emeritus Professor Keith Scott, Professor Paul Christensen

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Abstract

The electrochemical hydrodehalogenation (HDH) of 2,4-dibromophenol (DBP) has been carried out by electrochemical reduction in H-cells and solid polymer electrolyte (SPE) cells using catalysed cathodes. The electrochemical process gave high conversions of up to 95%, high selectivities of up to 98%, high current efficiencies of up to 98.5% and energy consumption as low as 2.2 kW h (kg DBP)-1. The type of the catalyst plays a decisive role in the efficiency of the HDH of DBP, with palladium being an attractive material. The effect of current density, DBP concentration, supporting electrolyte and temperature, on the HDH is reported.


Publication metadata

Author(s): Cheng H, Scott K, Christensen PA

Publication type: Conference Proceedings (inc. Abstract)

Publication status: Published

Conference Name: 6th European Symposium on Electrochemical Engineering

Year of Conference: 2003

Pages: 893-899

ISSN: 0021-891X

Publisher: Journal of Applied Electrochemistry, Springer

URL: http://dx.doi.org/10.1023/A:1025863711665

DOI: 10.1023/A:1025863711665

Library holdings: Search Newcastle University Library for this item

ISBN: 15728838


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