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Lookup NU author(s): Emeritus Professor Bill CleggORCiD,
Dr Mark Elsegood
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The title compound, C22H29NO4SSi, displays an anomeric effect in the marked shortening of one C-O bond relative to the other in the oxirane ring, concomitantly weakening the C-S bond to the arylthio substituent. This correlates with the selective reactivity of nucleophiles at the C atom having the longer C-O bond. The absolute configuration has been determined from anomalous scattering effects. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.
Author(s): Clegg W, Elsegood MRJ
Publication type: Article
Publication status: Published
Journal: Acta Crystallographica Section E: Structure Reports Online
Print publication date: 01/07/2003
ISSN (print): 1600-5368
Publisher: Wiley-Blackwell Publishing
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