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Lookup NU author(s): Dr Dr MD Harrison Harrison,
Professor Christopher Dennison
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Rapid fire! The replacement of the axial oxygen ligand at the type 1 copper site of stellacyanin with a weakly interacting thioether sulfur results in a fivefold increase in the electron self-exchange rate constant. This provides the first example of a type 1 copper site variant that exhibits increased reactivity and demonstrates that a site with an axial Met ligand is preferable for fast electron transfer, as shown.
Author(s): Harrison MD, Dennison C
Publication type: Article
Publication status: Published
ISSN (print): 1439-4227
ISSN (electronic): 1439-7633
Publisher: Wiley - VCH Verlag GmbH & Co. KGaA
PubMed id: 15515093
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