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(Dibenzo-18-crown-6)(2-phenylamidopyridine)-rubidium(I)

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Stephen Liddle

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Abstract

The title complex, [Rb(C11H9N2)(C 20H24O6)], has rubidium in an irregular eightfold coordination, with a hexadentate crown ether ligand and a chelating bidentate amidopyridine ligand, each occupying one hemisphere of the coordination. The chelate RbNCN ring is essentially planar, but the two rings of the amidopyridine ligand are not coplanar, because of steric interaction of H atoms on the rings. The Rb-N(amido) bond is shorter than the Rb-N(pyridine) bond. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved.


Publication metadata

Author(s): Clegg W, Liddle ST

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2004

Volume: 60

Issue: 10

Pages: m1492-m1494

Print publication date: 01/10/2004

ISSN (print): 1600-5368

ISSN (electronic):

Publisher: Wiley-Blackwell

URL: http://dx.doi.org/10.1107/S1600536804023359

DOI: 10.1107/S1600536804023359


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