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Lookup NU author(s): Emeritus Professor Bill CleggORCiD
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We have designed a new synthetic procedure to obtain multinuclear aggregates containing a {Pt2S2}n core. The synthetic strategy involves the reaction of [(dppp)Pt(μ-S) 2Pt(dppp)] with [PtCl2(PhCN)2] and thus the expansion of the {Pt2S2} ring to a [{Pt2S 2}PtCl2] fragment. The lability of the chloride anions allows their replacement by bridging sulfide ligands, thus affording a new [{Pt2(μ3-S)2}{Pt2(μ-S) 2}{Pt2(μ3-S)2}] core. Its subsequent evolution to [{Pt2S2}3PtCl 2] lays the foundation for a new cycle. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
Author(s): Mas-Balleste R, Clegg W, Lledos A, Gonzalez-Duarte P
Publication type: Article
Publication status: Published
Journal: European Journal of Inorganic Chemistry
Year: 2004
Volume: 2004
Issue: 16
Pages: 3223-3227
Print publication date: 20/08/2004
ISSN (print): 1434-1948
ISSN (electronic): 1099-0682
Publisher: Wiley-VCH Verlag GmbH & Co. KGaA,
URL: http://dx.doi.org/10.1002/ejic.200400257
DOI: 10.1002/ejic.200400257
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