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Feasibility study of electrochemical hydrodehalogenation of 2,4-dibromophenol in a paraffin oil

Lookup NU author(s): Dr Hua Cheng, Emeritus Professor Keith Scott, Professor Paul Christensen

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Abstract

The feasibility of electrochemical hydrodehalogenation (HDH) of 2,4-dibromophenol (DBP) in paraffin oil has been evaluated for short or long operation periods of up to 170h. HDH has been performed successfully using a solid polymer electrolyte reactor in a batch recycle mode with a dilute H 2SO4 aqueous solution as the anode feed and source of protons. The work reported in this paper expands the application of electrochemical HDH from aqueous systems to non-conductive media. The effect of the operating conditions, including current density, reactant concentration and temperature, is evaluated. The results are compared with those achieved in the aqueous solutions. © 2003 Elsevier Ltd. All rights reserved.


Publication metadata

Author(s): Cheng H, Scott K, Christensen PA

Publication type: Article

Publication status: Published

Journal: Electrochimica Acta

Year: 2004

Volume: 49

Issue: 5

Pages: 729-735

ISSN (print): 0013-4686

ISSN (electronic): 1873-3859

Publisher: Pergamon

URL: http://dx.doi.org/10.1016/j.electacta.2003.09.026

DOI: 10.1016/j.electacta.2003.09.026


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