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Conformational control of electron delocalisation in geometrically- constrained, binuclear ruthenium(II) bis(2,2′:6′,2″- terpyridine) complexes

Lookup NU author(s): Professor Andrew Benniston, Emeritus Professor Anthony Harriman, Dr Peiyi Li, Craig Sams

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Abstract

On the basis of temperature-dependent emission studies made with the target binuclear compounds, it is concluded that the extent of electron delocalisation at the triplet level depends on the torsion angle imposed by the bridge.

Publication metadata

Author(s): Benniston AC, Harriman A, Li P, Sams CA

Publication type: Article

Publication status: Published

Journal: Physical Chemistry Chemical Physics

Year: 2004

Volume: 6

Issue: 5

Pages: 875-877

ISSN (print): 1463-9076

ISSN (electronic): 1463-9084

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b316620a

DOI: 10.1039/b316620a

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