Toggle Main Menu Toggle Search

Open Access padlockePrints

The Newcastle University research output collection, currently available on ePrints, will shortly be moving to a new open repository platform, Figshare. To prepare for the data migration we have paused adding new content to ePrints, and will resume once the new repository is launched. During this time you will continue to have access to ePrints (but no new content will appear). We will share updates here when available.

Structural chemistry of halogenated monocarbaboranes: The extended structures of Cs[1-HCB9H4Br5], Cs[1-HCB 11H5Cl6] and Cs[1-HCB11H5Br6]

Lookup NU author(s): Professor William Clegg

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.

Abstract

The crystal structures of the Cs+ salts of the halogenated monocarbaborane anions [closo-1-HCB9H4Br5] -, [closo-1-HCB11H5Cl6]- and [closo-1-HCB11H5Br6]- have been determined. The structures show two-dimensional extended-sheet or three-dimensional lattice structures and feature unusual distorted cuboctahedral and tetrakis hexahedral coordination geometries about Cs+. Incidental to the structural work, new convenient preparations of the precursive non-halogenated monocarbaborane anions [closo-1-HCB9H 9]- and [closo-1-HCB11H11] - are presented.

Publication metadata

Author(s): Franken A, Bullen NJ, Jelinek T, Thornton-Pett M, Teat SJ, Clegg W, Kennedy JD, Hardie MJ

Publication type: Article

Publication status: Published

Journal: New Journal of Chemistry

Year: 2004

Volume: 28

Issue: 12

Pages: 1499-1505

ISSN (print): 1144-0546

ISSN (electronic): 1369-9261

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b410929e

DOI: 10.1039/b410929e

Altmetrics

Altmetrics provided by Altmetric

Share