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Lookup NU author(s): Emeritus Professor Bill CleggORCiD
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The crystal structures of the Cs+ salts of the halogenated monocarbaborane anions [closo-1-HCB9H4Br5] -, [closo-1-HCB11H5Cl6]- and [closo-1-HCB11H5Br6]- have been determined. The structures show two-dimensional extended-sheet or three-dimensional lattice structures and feature unusual distorted cuboctahedral and tetrakis hexahedral coordination geometries about Cs+. Incidental to the structural work, new convenient preparations of the precursive non-halogenated monocarbaborane anions [closo-1-HCB9H 9]- and [closo-1-HCB11H11] - are presented.
Author(s): Franken A, Bullen NJ, Jelinek T, Thornton-Pett M, Teat SJ, Clegg W, Kennedy JD, Hardie MJ
Publication type: Article
Publication status: Published
Journal: New Journal of Chemistry
ISSN (print): 1144-0546
ISSN (electronic): 1369-9261
Publisher: Royal Society of Chemistry
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