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Tetraethylammonium [1-methylimidazole-2(3H)-thione]copper(I)-di-μ- sulfido-dioxotungstate(VI)

Lookup NU author(s): Dr Neil Brooks, Emeritus Professor Bill CleggORCiD


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In the title complex, tetrethylammonium [1-methylimidazole-2(3H)-thione- 2κS]dioxo-1κ2O-di-μ-sulndo-1:2κ4-S: S-copper(I)tungstate(VI), (C8H20N)[WCuO2S 2(Hmimt)], where Hmimt is 1-methylimidazole-2(3H)-thione (C 4H6N2S), the Wand Cu atoms have tetrahedral and trigonal planar coordination, respectively. Two sulfide ligands bridge the two metal centres; tungsten is additionally coordinated by two terminal oxo ligands and copper by the exocyclic S atom of Hmimt. The bridged W⋯Cu distance is 2.670 (3) Å. Anions are linked into chains by N-H⋯O hydrogen bonds between Hmimt and oxo ligands. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved.

Publication metadata

Author(s): Beheshti A, Brooks NR, Clegg W, Khorrmdin R

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2004

Volume: E60

Issue: 12

Pages: m1923-m1926

ISSN (electronic): 1600-5368

Publisher: Wiley-Blackwell


DOI: 10.1107/S1600536804030132


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