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Asymmetric synthesis of cyanohydrins catalysed by a potassium Δ-bis[N-salicylidene-(R)-tryptophanato]cobaltate complex

Lookup NU author(s): Professor Michael North

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Abstract

A chiral cobalt(III) complex of a Schiff base derived from (R)-tryptophan and salicylaldehyde catalysed asymmetric trimethylsilylcyanation of benzaldehyde at ambient temperature and a 20:1 substrate/catalyst ratio with the formation of enantiomerically enriched mandelonitrile (ee up to 77%).

Publication metadata

Author(s): Belokon YN, Bulychev AG, Maleev VI, North M, Malfanov IL, Ikonnikov NS

Publication type: Article

Publication status: Published

Journal: Mendeleev Communications

Year: 2004

Volume: 14

Issue: 6

Pages: 249-250

Print publication date: 01/01/2004

ISSN (print): 0959-9436

ISSN (electronic): 1364-551X

Publisher: Elsevier BV

URL: http://dx.doi.org/10.1070/MC2004v014n06ABEH002029

DOI: 10.1070/MC2004v014n06ABEH002029

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