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Solvent-mediated variation of the terephthalate coordination mode in copper sulfimide complexes

Lookup NU author(s): Dr Sophie Dale, Dr Mark Elsegood

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Abstract

Reaction of copper(II) terephthalate and S,S′-diphenylsulfimide in MeOH gives a 1-D coordination polymer with inner-sphere terephthalate ligands; addition of H2O to the reaction solution, however, results in a hydrogen bonded array with the terephthalate anion acting as an outer-sphere ligand. © The Royal Society of Chemistry 2005.

Publication metadata

Author(s): Holmes KE, Kelly PF, Dale SH, Elsegood MRJ

Publication type: Article

Publication status: Published

Journal: CrystEngComm

Year: 2005

Volume: 7

Issue: 32

Pages: 202-205

ISSN (electronic): 1466-8033

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b500099h

DOI: 10.1039/b500099h

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