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Lookup NU author(s): Emeritus Professor Bill CleggORCiD,
Dr Sophie Dale
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(Chemical Equation Presented) Deprotonative metalation of ferrocene by a lithium zincate reagent was carried out to form the neutral zinc complex [(Fc)2Zn(tmeda)] and the anionic zincate [Li(thf)4][(Fc) 3Zn] (see scheme; tmp = 2,2,6,6-tetramethylpiperidine, TMEDA = N,N,N′,N′-tetramethylethylenediamine). A 1:1:1 mixture of TMEDA, Li(tmp), and nBu2Zn is used to readily prepare the lithium zincate reagent [LinBu2Zn(tmp)(tmeda)] in situ. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
Author(s): Barley HRL, Clegg W, Dale SH, Hevia E, Honeyman GW, Kennedy AR, Mulvey RE
Publication type: Article
Publication status: Published
Journal: Angewandte Chemie - International Edition
Print publication date: 19/09/2005
ISSN (print): 1433-7851
ISSN (electronic): 1521-3773
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