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The use of the bromosulfimide Ph2S=NBr as nitrogen source in reactions with selenium-based systems

Lookup NU author(s): Emeritus Professor Bill Clegg, Dr Sophie Dale

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Abstract

The use of the bromosulfimide Ph2S double bonded with NBr was analyzed as nitrogen source in reactions with selenium-based systems. The N-bromosulfimide Ph2S double bonded with NBr reacts with a range of selenium sources including, elemental selenium itself, to generate to explosive nitride Se4N4. Addition of solid Ph3PSe to an excess of the bromosulfide was dissolved in MeCN led to precipitation of an insoluble orange product. d. It was stated that reaction of the compound with selenium raises the possibility that the bromosulfide could be capable of acting as nitride source towards main group elements.


Publication metadata

Author(s): Clegg W, Dale SH, Drennan D, Kelly PF

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2005

Issue: 19

Pages: 3140-3142

ISSN (print): 1477-9226

ISSN (electronic): 1477-9234

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b509382a

DOI: 10.1039/b509382a


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