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A previously unrecognised hydronium di-cation in the crystal structure of a cucurbituril derivative

Lookup NU author(s): Emeritus Professor Bill Clegg

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Abstract

Examination of the crystal structure of the adduct of hydronium tetrachloroferrate dichloride with cucurbituril resulted in the discovery that the hydronium cation present therein is not the well known H7O 3+ species; rather, it is an unprecedented cyclic species of composition (H14O6)2+, templated by the formation of five hydrogen bonds to cucurbituril. © The Royal Society of Chemistry 2005.


Publication metadata

Author(s): Bernal I, Mukhopadhyay U, Virovets AV, Fedin VP, Clegg W

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2005

Issue: 30

Pages: 3791-3792

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b505641c

DOI: 10.1039/b505641c


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