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New titanium and zirconium complexes with M-NH2 bonds formed by facile deprotonation of H3N·B(C6F5) 3

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Ross Harrington

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Abstract

Facile deprotonation of H3N·B(C6F 5)3 with [M(NMe2)4] (M = Zr or Ti) yields the novel amidoborate complexes [Zr(NMe2)3-{NH 2B(C6F5)3}(HNMe2)] and [Ti(NMe2)3{NH2B(C6F 5)3}]. © The Royal Society of Chemistry 2005.

Publication metadata

Author(s): Mountford AJ, Clegg W, Harrington RW, Humphrey SM, Lancaster SJ

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2005

Issue: 15

Pages: 2044-2046

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b500407a

DOI: 10.1039/b500407a

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