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N - H⋯S and N - H⋯O hydrogen bonding in tetra-n-butylammonium (imidazolidine-2-thione-2κS)dioxo-1κ2O-di-μ-sulfido- 1:2κ4S:S-copper(I)tungstate(VI)

Lookup NU author(s): Emeritus Professor Bill CleggORCiD, Dr Sophie Dale


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In the title complex, (C16H36N)[WCuO 2S2(C3H6N2S)], the W and Cu atoms have tetrahedral and trigonal-planar coordination, respectively. Two sulfide ligands bridge the two metal centres; tungsten is additionally coordinated by two terminal oxo ligands and copper by the exocyclic S atom of imidazolidine-2-thione. There is an intramolecular N - H⋯S hydrogen bond in the anion, and anions are linked into chains by N - H⋯O intermolecular hydrogen bonds. The more loosely held cation is disordered. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.

Publication metadata

Author(s): Beheshti A, Clegg W, Dale SH, Solimankhani A

Publication type: Article

Publication status: Published

Journal: Acta Crystallographica Section E: Structure Reports Online

Year: 2005

Volume: 61

Issue: 8

Pages: m1509-m1511

ISSN (print): 1600-5368

ISSN (electronic):

Publisher: Wiley-Blackwell Publishing, Inc.


DOI: 10.1107/S1600536805021628


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