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Lookup NU author(s): Emeritus Professor Bill Clegg,
Dr Sophie Dale
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In the title complex, (C16H36N)[WCuO 2S2(C3H6N2S)], the W and Cu atoms have tetrahedral and trigonal-planar coordination, respectively. Two sulfide ligands bridge the two metal centres; tungsten is additionally coordinated by two terminal oxo ligands and copper by the exocyclic S atom of imidazolidine-2-thione. There is an intramolecular N - H⋯S hydrogen bond in the anion, and anions are linked into chains by N - H⋯O intermolecular hydrogen bonds. The more loosely held cation is disordered. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
Author(s): Beheshti A, Clegg W, Dale SH, Solimankhani A
Publication type: Article
Publication status: Published
Journal: Acta Crystallographica Section E: Structure Reports Online
ISSN (print): 1600-5368
Publisher: Wiley-Blackwell Publishing, Inc.
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