Toggle Main Menu Toggle Search

Open Access padlockePrints

Crystallographic characterisation of binary alkali metal alkoxide-magnesium bis(alkyl) mixtures: Differential binding of Na+ and K+ to a common dinuclear diorganomagnesiate

Lookup NU author(s): Emeritus Professor Bill Clegg

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.


Abstract

Relevant to mixtures studied in solution and utilised in styrene polymerisation but hitherto not characterised in the solid, two crystal structures of alkali metal alkoxide-magnesium bis(alkyl) co-complexes have been determined, revealing that in binding to the C2O tripodal face of a common organomagnesiate anion, Na+ prefers O-coordination, whereas K+ prefers C-coordination.


Publication metadata

Author(s): Barnett NDR, Clegg W, Kennedy AR, Mulvey RE, Weatherstone S

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2005

Issue: 3

Pages: 375-377

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b413191f

DOI: 10.1039/b413191f


Altmetrics

Altmetrics provided by Altmetric


Actions

Find at Newcastle University icon    Link to this publication


Share