ePrints

A chiral amide derivative with the β-P₄S₃ cage skeleton

Lookup NU author(s): Dr Bruce Tattershall

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.

Abstract

The diamide exo,exo-β-P4S3(NHCH(Me)Ph) 2 has been made in solution using enantiomerically pure or racemic PhCH(Me)NH2, and its three diastereomers characterised by complete analysis of their 31P{1H} NMR spectra. The unsymmetric diastereomer contains phosphorus atoms, made chemically non-equivalent by the chirality of the substituents, which show a large 2J(P-P-P) coupling to each other (225.2 Hz). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

Publication metadata

Author(s): Tattershall BW, Booth CL

Publication type: Article

Publication status: Published

Journal: Zeitschrift fur Anorganische und Allgemeine Chemie

Year: 2005

Volume: 631

Issue: 5

Pages: 857-860

Print publication date: 01/04/2005

ISSN (print): 0044-2313

ISSN (electronic): 1521-3749

Publisher: Wiley

URL: http://dx.doi.org/10.1002/zaac.200500001

DOI: 10.1002/zaac.200500001

Altmetrics

Share