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Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment

Lookup NU author(s): Dr Ross Harrington, Emeritus Professor Bill Clegg

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Abstract

The reaction of (η5-C5H5)Fe(CO) 2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [η5-C5H4B(C6F 5)2H]Fe(CO)3 in quantitative yield. © The Royal Society of Chemistry 2006.


Publication metadata

Author(s): Aldridge S, Kays DL, Al-Fawaz A, Jones KM, Horton PN, Hursthouse MB, Harrington RW, Clegg W

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2006

Issue: 24

Pages: 2578-2580

Print publication date: 01/01/2006

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b604141h

DOI: 10.1039/b604141h


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